Reversible photochromic switching in a Ru(II) polypyridyl complex.
نویسندگان
چکیده
Fully reversible photoswitching of the coordination mode of the ligand MeN4Py (1,1-di(pyridin-2-yl)-N,N'-bis(pyridin-2-yl-methyl)-ethan-1-amine) in its ruthenium(II) complex with visible light is reported. Irradiation with visible light results in dissociation of a pyridyl moiety, which is reversed by irradiation at 355 nm.
منابع مشابه
Mechanistic insights into electrocatalytic CO2 reduction within [Ru(II)(tpy)(NN)X]n+ architectures.
A series of Ru(II)-polypyridyl complexes of the design [Ru(II)(tpy)(NN)X](n+) (tpy = 2,2':6',2''-terpyridine; NN = bidentate polypyridine; X = Cl(-) or CH3CN; n = 1 or 2) have been synthesized and analyzed for their ability to function as electrocatalysts in the reduction of CO2 to CO. Varying the electron-donating/withdrawing character of the NN polypyridyl ligand has allowed for modification ...
متن کاملConstruction of a photoactive supramolecular system based on a platinum(II) bis-acetylide building block incorporated into a ruthenium(II) polypyridyl complex.
A new ruthenium(ii) polypyridyl-platinum(ii) diethynyl triad containing 3-ethynylphenanthroline linked by platinum(ii) bis-tributylphosphine organometallics, Ru(ii)-Pt(ii)-Ru(ii), and platinum(ii) bis-ethynylphenanthroline complex has been prepared. The ruthenium(ii)-metal triads, Ru(ii)-M-Ru(ii) (M = Pt(ii) and Au(i)), showed typical MLCT absorption bands and a lowest energy pi-pi* absorption ...
متن کاملDNA binding, cytotoxicity, and apoptotic-inducing activity of ruthenium(II) polypyridyl complex.
There is considerable interest in the interactions of ruthenium (Ru)(II) complexes with DNA as well as the biological impact of the interactions. Here, by using isothermal titration calorimetry, viscosity measurement, and circular dichroism, we investigated the interactions of a new Ru(II) complex, [Ru(dmp)(2)PMIP](2+){dmp = 2,9-dimethyl-1,10-phenanthroline, PMIP = 2-(4-methylphenyl)imidazo[4,5...
متن کاملPushing the limit: synthesis, photophysical and DNA binding studies of a NIR-emitting Ru(II)-polypyridyl probe with 'light switch' behaviour.
The new Ru(II) polypyridyl complex 1 was synthesised using microwave irradiation from the new polypyridyl ligand 2'DipyTAP', and its photophysical properties, and DNA binding abilities were investigated using various spectroscopic techniques; and 1 was shown to act as a 'NIR molecular light switch' for DNA with an emission window between 680 and 860 nm.
متن کاملSolvent-dependent aggregation behavior of a new Ru(II)-polypyridyl based metallosurfactant.
Variation of the solvent polarity leads to the formation of vesicles and reverse vesicles of a newly synthesized amphiphilic Ru(II)-polypyridyl complex.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Dalton transactions
دوره 43 45 شماره
صفحات -
تاریخ انتشار 2014